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polymer
Columbia Encyclopedia entry: polymer
Polymerpŏl'əmər, chemical compound with high molecular weight consisting of a number of structural units linked together by covalent bonds (see chemical bond). The simple molecules that may become structural units are themselves called monomers; two monomers combine to form a dimer, and three monomers, a trimer. A structural unit is a group having two or more bonding sites. A bonding site may be created by the loss of an atom or group, such as H or OH, or by the breaking up of a double or triple bond, as when ethylene, H2C˭CH2, is converted into a structural unit for polyethylene, ‒H2C‒CH2‒. In a linear polymer, the structural units are connected in a chain arrangement and thus need only be bifunctional, i.e., have two bonding sites. When the structural unit is trifunctional (has three bonding sites), a nonlinear, or branched, polymer results. Ethylene, styrene, and ethylene glycol are examples of bifunctional monomers, while glycerin and divinyl benzene are both polyfunctional. Polymers containing a single repeating unit, such as polyethylene, are called homopolymers. Polymers containing two or more different structural units, such as phenol-formaldehyde, are called copolymers. All polymers can be classified as either addition polymers or condensation polymers. An addition polymer is one in which the molecular formula of the repeating structural unit is identical to that of the monomer, e.g., polyethylene and polystyrene. A condensation polymer is one in which the repeating structural unit contains fewer atoms than that of the monomer or monomers because of the splitting off of water or some other substance, e.g., polyesters and polycarbonates (see illustration). Many polymers occur in nature, such as silk, cellulose, natural rubber, and proteins. In addition, a large number of polymers have been synthesized in the laboratory, leading to such commercially important products as plastics, synthetic fibers, and synthetic rubber. Polymerization, the chemical process of forming polymers from their component monomers, is often a complex process that may be initiated or sustained by heat, pressure, or the presence of one or more catalysts.
Wikipedia search results for: Polymer
From Wikipedia, the free encyclopedia
A polymer is a large molecule composed of repeating structural units typically connected by covalent chemical bonds. While polymer in popular usage suggests plastic, the term actually refers to a large class of natural and synthetic materials with a variety of properties. Due to the extraordinary range of properties accessible in polymeric materials Painter, p. 1 , they have come to play an essential and ubiquitous role in everyday life McCrum, p. 1 —from plastics and elastomers on the one hand to natural biopolymers such as DNA and proteins that are essential for life on the other. A simple example is polyethylene, whose repeating unit is based on...more »
Columbia Encyclopedia search results: polymer
Results 1 - 10  of 55
  • thermoplastics

    Thermoplastics, materials that soften or melt when heated and harden when cooled. Thermoplastic polymers consist of long polymer molecules that are not linked to each other. i.e., have no cros...

  • thermosets

    Thermosets, materials that can not be softened on heating. In thermosetting polymers, the polymer chains are joined (or cross-linked) by intermolecular bonding. Thermosets are usually supplied...

  • polyolefins

    Polyolefins, group of plastics that are polymers of various alkenes, or olefins. The most important are polyethylene and polypropylene.

  • polycarbonates

    Polycarbonates, group of clear, thermoplastic polymers used mainly as molding compounds (see plastic). Polycarbonates are prepared by the reaction of an aromatic difunctional phenol with eithe...

  • macromolecule

    Macromolecule, term that may refer either to a crystal such as a diamond, in which the atoms are identical and held by covalent bonds (see chemical bond) of equal strength, or to one of the un...

  • polyvinyl chloride

    Polyvinyl chloride (PVC), thermoplastic that is a polymer of vinyl chloride. Resins of polyvinyl chloride are hard, but with the addition of plasticizers a flexible, elastic plastic can be mad...

  • actin

    Actin, a protein abundantly present in many cells, especially muscle cells, that significantly contributes to the cell's structure and motility. Actin can very quickly assemble into long polym...

  • glycogen

    Glycogen, starchlike polysaccharide (see carbohydrate) that is found in the liver and muscles of humans and the higher animals and in the cells of the lower animals. Chemically it is a highly ...

  • polyacrylics

    Polyacrylics, group of thermoplastics that are transparent and highly decorative (see plastic). The polyacrylics, or acrylic plastics, are polymers (and copolymers) of derivatives of acrylic a...

  • synthetic textile fibers

    Synthetic textile fibers have revolutionized the textile industry. Such artificial fibers are usually long-chain polymers, produced industrially by the condensation of many small units. Orlon ...

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