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plutonium
Columbia Encyclopedia entry: plutonium
Plutoniumplootō'nēəm, radioactive chemical element; symbol Pu; at. no. 94; mass no. of most stable isotope 244; m.p. 641°C; b.p. 3,232°C; sp. gr. 19.84 at 20°C; valence +3, +4, +5, or +6. Plutonium is a silver-gray radioactive metal that has six allotropic forms (see allotropy). It is a member of the actinide series in Group 3 of the periodic table. It is chemically reactive. It tarnishes in air, taking on a yellow cast when oxidized. It dissolves in hydrochloric, hydriodic, and perchloric acids and reacts with the halogens, carbon, nitrogen, and silicon. Plutonium, the second transuranium element, was named for Pluto, then regarded as the second planet beyond Uranus. Plutonium is found naturally in very small quantities in association with uranium ores. However, it was discovered in 1940 at the Univ. of California at Berkeley by Glenn T. Seaborg, Edwin M. McMillan, Joseph W. Kennedy, and Arthur C. Wahl; using a cyclotron to bombard uranium oxide with deuterons, they produced plutonium-238 (half-life about 87 years). Fifteen additional isotopes of plutonium are known. The most stable is plutonium-244 (half-life about 82 million years). By far the most important is plutonium-239 (half-life about 24,000 years), a nuclear fission fuel. It is produced in large quantities in nuclear reactors from uranium-238, an abundant but nonfissionable isotope. Uranium-238 absorbs neutrons emitted by the fission of uranium-235; uranium-239 is formed, which emits a beta particle and decays to neptunium-239; the neptunium-239 emits another beta particle, becoming plutonium-239. Once begun, the reaction proceeds spontaneously until the uranium fuel rods in the reactor are converted to a certain uranium-plutonium mixture. The rods are dissolved in acid and the plutonium separated by chemical means, especially by solvent extraction. Pure plutonium metal may be prepared by reduction of the trifluoride, PuF3, with calcium metal. Plutonium is important for its use in nuclear weapons and nuclear reactors. Plutonium-238 has been used to power scientific equipment in lunar exploration and implanted heart pacemakers (see pacemaker, artificial). Plutonium is an extremely dangerous poison; it collects in the bones and interferes with the production of white blood cells.
Wikipedia search results for: Plutonium
From Wikipedia, the free encyclopedia
Plutonium is a rare transuranic radioactive chemical element with the chemical symbol Pu and atomic number 94. It is an actinide metal of silvery-white appearance that tarnishes when exposed to air, forming a dull coating when oxidized. The element normally exhibits six allotropes and four oxidation states. It reacts with carbon, halogens, nitrogen and silicon. When exposed to moist air, it forms oxides and hydrides that expand the sample up to 70% in volume, which in turn flake off as a powder that can spontaneously ignite. It is also a radioactive poison that accumulates in bone marrow. These and other properties make the handling of plutonium...more »
Columbia Encyclopedia search results: plutonium
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  • Periodic Table of the Elements: Plutonium

    Periodic Table of the Elements: PlutoniumAtomic Number:94Atomic Symbol:PuPlutoniumAtomic Weight:(244)ElectronConfiguration:2 · 8 · 1832 · 248 · 2

  • Pu

    Pu, symbol for the element plutonium.

  • hydrogen bomb

    Hydrogen bomb or H-bomb, weapon deriving a large portion of its energy from the nuclear fusion of hydrogen isotopes. In an atomic bomb, uranium or plutonium is split into lighter elements that...

  • Manhattan Project

    Manhattan Project, the wartime effort to design and build the first nuclear weapons (atomic bombs). With the discovery of fission in 1939, it became clear to scientists that certain radioactiv...

  • Richland

    Richland, city (1990 pop. 32,315), Benton co., S Wash., at the confluence of the Columbia and Yakima rivers, in an irrigated farm and vineyard region; inc. 1958. It is the headquarters of the ...

  • Hierapolis

    Hierapolis, ancient city of Phrygia, W Asia Minor, 7 mi (11.3 km) N of Laodicea and on a plateau 500 ft (152 m) above the Lycus valley (in present-day Turkey). Devoted to the worship of Leto i...

  • Lanzhou

    Lanzhou or Lanchow, city (1994 est. pop. 1,295,600), capital of Gansu prov., W China, on the Huang He (Yellow River) at its confluence with the Wei. It is a rail, highway, and air hub and the ...

  • McMillan, Edwin Mattison

    McMillan, Edwin Mattison, 1907–91, American physicist, b. Redondo Beach, Calif., grad. California Institute of Technology, 1928, Ph.D. Princeton, 1932. On the faculty of the Univ. of Californi...

  • fermium

    Fermium [for Enrico Fermi], artificially produced radioactive chemical element; symbol Fm; at. no. 100; mass no. of most stable isotope 257; m.p. 1,527°C; b.p. and sp. gr. unknown; valence +2,...

  • actinide series

    Actinide series, a series of radioactive metallic elements in Group 3 of the periodic table. Members of the series are often called actinides, although actinium (at. no. 89) is not always cons...

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